EXAFS的分辨率和信噪比与实验参数间相互关联的探讨

A Study of the Relationship Between the Resolution Signal to Noise Ratio and the Experimental Data of EXAFS

  • 摘要: 本文详细讨论了EXAFS测定的分辨本领、信噪比与实验参数间的相互关联;提出了实验参数临界条件的概念及其确定的方法;在临界条件下分别讨论了分辨本领、信噪比与临界实验参数值的相互关系并由此导出如下结论:1.当入射狭缝,出射狭缝宽度均为临界参数时,EXAFS测定的分辨本领与分光晶体摆动曲线的宽度无关,而信噪比则取决于分光晶体摆动曲线宽度所表征的嵌镶块大小对强度分布和消光效应的影响。2.当接收狭缝,分光晶体摆动曲线的宽度均为临界参数时,入射狭缝可增至最佳宽度,其分辨本领不仅保持不变,还能显著提高信噪比。当入射狭缝继续增大,超过最佳宽度时,信噪比不再增加。文中由此指出:当所用分光晶体完整性欠佳时,以采用结论1的条件为宜;当分光晶体完整性较好则应采用用结论2所提出的条件。

     

    Abstract: This paper describes in detail the relationship between the resoluttion, signal to noise ratio and the experimental data from EXAFS measurement.It has been presented the opinion of critical condition for experimental data and the method of a precise measurement. The relationship between resolution, singnal to noise ratio and the critical experimental data have been discussed and the following conclutions have been introduced at the critial condition:
    1. The resolution is independent on the rocking curve width of the monochromator crystal when the width of entrance slit and exit slit both equal to the critial data but the signal to noise ratio depends on which is more important to the mosaic structure size that is characte-rized by the rocking curve wicth of the mono-chromactor crystal:the intensity distribution or the extinction effect.
    2. The entrance slit width increases to the optimum that the resolution keepsa constant and the signal to noise ratio increase obviously wh the width of exit slit and the rocking curve of monochromator crystal equal to the critical data. But the signal to noise ratio does not in crease with the entrance slit width if the width is largerth an the op timura.
    It has been shown in the paper that the conclution 1 is more suitable to that where the perfection of the monochromator crystal is not good enoughi and the conclution 2 is fit to perfect crystal.

     

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