12SiMoVNb抗氢钢碳化物与抗氢腐蚀关系

The Relation of Hydrogen Attack and Alloy Carbides in steel 12SiMoV Nb Steel

  • 摘要: 抗氢钢中形成稳定的合金碳化物以固定碳,避免在高温、高压下与氢作用形成甲烷造成氢损伤,这不仅与钢材成分的合理设计有关,而且与合理选择热处理制度密切有关。本文采用综合相分析方法对12SiMoVNb合金碳化物析出及其与氢相互作用行为进行探讨,指出采用~1000℃正火及720℃~740℃高温回火,以获得在铁素体基体上分布着以V4C3为主的弥散碳化物,以及Mo、V、Nb元素固溶强化是该合金获得综合力学性能,特别是高温(400℃PH2=200kg/cm2)抗氢腐蚀性能的关健。

     

    Abstract: In the hydrogen resistant steel alloy carbides are formed to fix carbon so as to avoid the formation of methane at Fe3C, that causes hydrogen damage.This Process depends not only on an appropriate design of the steel composition, but also on aproper selection of heat treatment This research was doneby using complex phase analysis method to study the precipitation of alloy carbides and their relationship with hydrogen in 12SiMoVNb steel.
    By normanizatibn at lOOO℃ and tempering at 720-740tJ small carbides (most one of them is V4C3) distribute in the ferrite matrix and solid solution strengthening by Mo% V, Nb were obtained. They are both decisive factors in achieveing good arc mechanical properties and promoting the resistance against hydrogen attack at 400t and at PH2-200 kg/cm2.

     

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