钢水喷镁精炼及其对钢性能的影响
Steel Refining by Magnesium Injection and its Influence on Steel Quality
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摘要: 由于镁对钢的脱氧、脱硫、净化钢水及转变夹杂物形态的良好作用,近年来许多冶金工作者致力于加镁精炼钢水的研究工作,但因在冶金温度下镁的蒸汽压很高,而其在钢水的溶解度又极小,加入困难,这方面的研究多归于失败。本文利用阿亨大学热力学数据库计算了以氩作为载气喷镁的脱氧、脱硫作用,以及压力和氩量对其影响,通过实验制定了行之有效的喷吹工艺,选择了合适的控制参数。
在1-3大压下,氩量为0.1-0.3N.L/m:n,可以向钢水成功地喷入镁。经过镁精炼的钢水,氧含量可降至4ppm,硫含量降至10ppm,氧化物及硫化物的评级均为0级,其尺寸均在5μm之下。随着喷镁量的增加(钢水重量的0.062至%0.56%),夹杂物中镁的氧化物及硫化物量增加,夹杂物总量减少且呈球形,此种夹杂物在热形变中不变形。因此在通常材料中所存在的各向异性完全消失,特别是缺口冲击韧性横向性能值提高了2~3倍。文章对材料在不同温度下的冲击韧性、过渡温度及断口夹杂物的形态进行了研究和论述。Abstract: Recentl man metallurgists heve been working with steel refining by using maganesium as deoxidizer and desflfurizer which also leads to better morphology of nonmetallic inclusions. That it might be very difficult to add maganesium in was the reason for the previous works to fail. The trouble is that the partial pressure of maganesium is very high at the melting temperatures and at the same time its solubility in the liquid steel is rather small. In this article, the effect of injecting Mg-powder on deoxidation and desulfurization by using Ar-gas as carrier based on thermcdynamic data stove in Aachen university and the effects of the pressure and flow of Ar-gas on the technology mentioned above have been calculated. The effective injecting technology was determined experimeutally and the appropriate controlling parameters were chosen.
Maganesium can be successfully insected into the liquid steel at 0.1~0.3NL/min of Ar-gas flow under 1-3 atm. The oxygen content was decreased to 4ppm in the liquid steel to be refined. The sulfur content 10ppm. The graduation of oxides and sulfides was 0-grade. This sizes are less than 5μm. Mg-oxides and sulfides in the inclusions were increased with the increase of amount of injecting maganesium. However the total amount of inclusions were decreased and the shape appears as sphere. The inclusions remain unchanged shape during hot deformation. The anisotropic characteristic which usually exists in materials disappeared completely especially the notch-impact toughness at the transverse direction was increased by 2-3 times. The impact toughness at the different temperatures the transition temperatures and the inclusion shapes on the fractures for the materials to be refine 1 were also discussed.