纯铁小颗粒中的马氏体相变
The Martensitic Transformation in Small Pure Iron Particles
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摘要: 当使用Ar+离子轰击Cu-Fe合金薄膜试样时,试样中所存在的fcc亚稳状态小铁颗粒将发生马氏体相变。定量立体电子显微术的试验结果表明:(a)马氏体相交只限于在那些临近试样表面的小铁颗粒内发生(b)尽管试样的下表面不受Ar+离子的轰击,也浸有幅射缺陷存在,但靠近下表面的小铁颗粒仍然发生了马氏体相变。可见,由于离子轰击所引起的弹性表面波(Rayleigh Waves)是促成相变产生的原因。
受轰击试样的高分辨率晶格象表明上述的马氏体相变又可分为二种类型:部份型转变(Partially transformation)和整体型转变(fully transformation)。其中,整体型转变后的小铁颗粒具有孪晶型组织,使用一般的透射电子显微镜也能看到;而部份型转变后的小颗粒里则含有很薄的马氏体片层,这些马氏体片平行于未转变区内奥氏体的致密排列面。整体型转变只是在试样表面处的小铁颗粒内发生,原因可能是这里的小铁颗粒有着足够的自由表面。而部份型转变则是在被铜基体完全包裹着的颗粒内发生。Abstract: When Thin foil Specimens of Copper-iron alloys Containing metastable fcc r-iron are bombarded with argon ions the precipitates are induced to transform martensitically to bcc iron. Using stereo microscopy technigues it was established that (1) transformation is limited to those particles near the Surfaces of the Specimen, (2) Particles on the non-irradiated Surface Can transform even when the irradiation damage does not extend so far. The transformation is therefore thought to be initiated by elastic Surface (Rayleigh) waves Set up by the ion impacts.
High resolution lattice fringe electron microscopy of bombarded Specimens Showed that both partially transformed and fully transformed Precipitates exist. The fully transformed precipitates have the twin structure already Seen with Conventiond TEM, but the partially transformed precipitates Contain Very thin laths or plates of martensite Parallel to the Close-packed planes of the untransformed fcc regions. Complete transformation is thought to be associated with partides that have a substantial amount of free Surface, while Partial transformation is probably Characteristic of particles that are fully constrained by the copper matrix.