MgO在人造富矿中的赋存状态及作用

The existing state of Mgo and it effect on the properties of iron ore agglomerates

  • 摘要: 本文采用光学显微镜,电子探针及穆斯堡尔效应等手段对MgO在烧结矿和球团矿中的赋存状态及其对冶金性能的影响进行了微观分析研究。
    显微镜下观察表明,随烧结矿中MgO含量增加,赤铁矿及铁酸钙明显减少。当MgO约达4%以上时,烧结矿渣相中开始出现少量镁质硅酸盐矿物。
    电子探针扫描分析表明,MgO主要分布于除赤铁矿之外的铁相矿物中,在烧结矿中形成含镁磁铁矿,在球团矿中形成镁铁矿,少部分分布于渣相中。
    对杭钢球团矿所做的穆斯堡尔谱学研究表明,在焙烧过程中,Mg2+大量进入磁铁矿八面体晶位,揭示了MgO在人造富矿中富集于铁相及引起物相变化的机理。
    基于上述试验研究,分析了MgO对人造富矿冶金性能的影响。

     

    Abstract: By optical microscopic analysis, electron probs micro-analysis and Mössbauer effect, the existing state of Mgo and its effecf on the properties of sinter and pellet were studied, from optical microscopic observation, it was shown that as the Mgo content in sinter increased, the content of hematite and calciumferrite obviously decreased, when it reached more than 4%, some magnesiosilicate salt minerals in sinter slag was occured It was also found by electron probe micro-analysis that the Mgo mainly presented in iron oxide compound except hematite,such as magnesiomagnetite in sinter and magnesioferrite in pellet, and a small part of Mgo existed in slag phase. Large amount of Mg2+ entered in octahedron sites of magnetite of pellet of Hangchow stael works during induration period has been examined by use of Mossbausr effect which was ascertaind the mechanism of Mgo concentrated into iron oxide compound and changed the mineral constitasnts of iron ore agglomerates
    from avove investigation the effect of Mgo on the metallurgical properties of iron ore agglomerates was abtained.

     

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