铸钢和锻钢应力腐蚀性能的对比研究
Investigation of stress Corrosion Cracking of the Cast and Forging Steel in Water
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摘要: 用同一炉钢的铸件和锻件对比研究了在水介质中的应力腐蚀性能,结果表明,铸钢和锻钢应力腐蚀裂纹扩展的激活能相同,均为Q=5540cal/mol。且和氢渗透测出的表观扩散激活能Q=6010cal/mol相—致。无论是阳极极化还是阴极极化均使铸钢和锻钢的da/dt升高,但阴极极化更为明显,氢渗透测量表明,无论是阳极极化还是阴极极化,随电流增大,饱和氢渗透通量明显增加;极化对da/dt和氢渗透通量影响是相似的。
实验表明,试验温度对KIscc影响极小,但铸钢的KIscc明显比锻钢要高。氢渗透测试表明,锻钢的饱和氢渗透通量约比铸钢要大一倍,这就可解释KIscc的差异,这也和断口观察相一致,尽管断口形貌明显依赖开裂时的KI值,但在KIscc附近锻钢全是沿晶断口,而铸钢则以准解理为主。Abstract: stress corrosion behavior of the cast and forging steel with the same heat has been investigated.Results showed that the activation energy of crack growth of the cast steel was identical with that of the forging steel and was in agreement with the apparent diffusion activation energy of hydrogen in the steel.Both cathodic and anodic polarization increased the da/dt of the cast and forging steel but the influence of the cathodic polarization was much s-tronger. Correspondingly, the steady-stat hydrogen permeation flux increased steeply with increasing the polarization current, whether cathodic or anodic polarization.
The KISCC of the cast steel was larger than that of the forging steel. It may be due to the fact that the steady-stat hydrogen permeation flux of the forging steel was twice as larger as that of the cast steel.The fracture modes of both cast and forging steel were clearly dependent upon K1 at the crack tip and a transition from dimple to quasi-cleavage or intergranular was observed on the fracture surfaces with decreasing K1.