高锰钢中铈的溶质平衡分配系数K0的测定及铈对锰、硅K0值的影响

The Measurement of Cerium Equilibrium Partition Coefficient Ko and Influence of Cerium on Value of Manganese and Silicon Ko in High Manganese Steel

  • 摘要: 本实验采用定向凝固,固-液界面成分瞬时平衡的方法测定了铈在高锰钢中的平衡分配系数K0及铈对锰、硅元素K0的影响。铈及锰、硅元素在固-液界面附近固相和液相中的分布是用电子探针微区分析仪测定的。
    试验结果表明:定向凝固,固-液界面成分瞬时平衡方法是测定稀土元素K0值的有效方法,由此法测得铈在高锰钢中的K0值说明了铈在奥氏体中有微量固溶。同时测得锰的K0值随含铈量的增加而增加,硅的K0值随铈量的增加而减少。

     

    Abstract: This experiments is used by directional solidification technique and solid-liquid interfacial solute temporal equiliprium methed. It measured cerium equilibrium partition coefficient Ko and studied influence of cerium on manganese and silicon Ko in high manganese steel. Electronic prob microanalysis are used to measure the solute distribution of Ce. Mn. Si in solid and liquid at adjacent of solid-liquid interface.
    The results have shown that directional solidification and solid-liquid interfacail solute temporal equilibrium methed is effectivety me-thed with which the. Ko of rare-earth elements are measured. The Value of cerium Ko measured in high manganese steel show that cerium can slightly be solved in austerite. When cerium content increase the Ko of manganese increases, whereas Ko of silicon decreases.

     

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