高硫铁水变质处理新方法

Investigation of Modifying Treatment with Rare-Earth Oxide for High-sulphur Moltem

  • 摘要: 动用稀土氧化物固态渣饼作为脱硫剂和变质剂,借助吹氩搅拌对高硫(S=0.100%)过共晶铁水进行变质处理。实验在1450℃下进行30~45分钟得到了变质处理过程中铁水化学成分变化的规律和在过共晶铁水条件下试样中石墨形态和RE、CE含量之间的规律。
    结果表明在过共晶区当RE%≤(CE%-4.30%)/25时试样石墨形态为蠕虫状。当RE%≥(CE%-4.30%)/25时试样石墨形态为球状。对脱硫反应和稀土氧化还原反应进行了热力学计算和讨论,在实验条件下上述反应在热力学上均成立。

     

    Abstract: Applying solid slag Cakes of rare earth oxide as a desulphurizinga gent as well as a modifying agent and under Condition of Ar-blowing, a hy-pereutictic hot metal of high Sulphur content (s=0.100%) has been mo-difyied. Experiments are made at 1450 ℃ for about 30~35 minutes.
    Changeing laws of chemical composition in hot metal and relationship between graphite morphogy and contentof RE, CE in casting are abta-ined. Results indicate that the RE% ≤ (CE%-4.30%)/25 and the RE% ≥ (CE%-4.30%)/25 canbe abtained vermicalar cast iror and nodular cast iron respectively under hypereutectic hot metal. with regrad to disuph-urizing reaction and redwction reaction of rare earth oxrde, discussion and thermodynamic calculation have been Carried out. The results point out that the above mentioned reaction are all established thermodyra-mically umder the experimental condition.

     

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