电镀锡、铅锡镀层与基体铜形成化合物的动力学和引线可焊性

THE INVESTIGATIONS OF THE KINETICS ON INTERMETALLIC COMPOUND GROWTH AT THE INTERFACE OF THE SUBSTRTE COPPER AND TIN OR TIN-LEAD COATING AND THE SOLDERABILITY

  • 摘要: 本文对电镀锡和含64~76%Sn的铅锡镀层的铜导线进行了铜锡金属间化合物生长速度的研究。在100±1℃和155±2℃的温度下,经不同的老化时间后测定了化合物层的厚度,并得到了化合物生长厚度与时间、温度的关系式。实验测得在共晶成分附近的铅锡镀层其化合物生长速度快于纯锡镀层。引线在室温下放置近一年未发现可见的化合物层。本文还讨论了剩余镀层厚度与引线可焊性的关系。

     

    Abstract: The studies ot copper-tin intertnetallic compounds growth rates at the interface of the copper substrate and tin or lead-64-76% tin coating were conducted in this paper. The thickness of intermetallic compound layers formed with a variety of aging time at 100±1℃ and 155±2℃ had been measued. The dependences of the intermetallic compound thickness on time and temperature were shown. It had experimentally been observed that the growth rate of compound in lead-tin coating at near eute-ctic point is faster than that in purely tin coating. The compound layers have not been detected on the leader which had been stored at room temperature for about a year. In addition, the relationship between the remaining coating and the solderability of leader was also discussed.

     

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