耐大气腐蚀钢的氧化皮结构分析

The Microstructure of Scale for Corrosion Resistant Steel

  • 摘要: 本文探讨了耐蚀钢的氧化皮物相组成、显微结构与钢耐蚀性的关系。冷轧板氧化皮的物相组成为纤铁矿、非晶质氢氧化铁以及金属铁颗粒。耐蚀性好的钢,纤铁矿发育,“港湾状”锈蚀现象少;反之则以非晶质氢氧化铁为主,氧化皮中金属颗粒也较多。热轧板除上述物相外,主要为磁铁矿与赤铁矿。各物相有分带现象。磁铁矿带发育、氧化皮与金属呈锯齿状镶嵌者耐蚀性好。
    加有稀土元素的热轧板,稀土元素能净化钢质、球化夹杂物,也能抑制氧化皮中磁铁矿等在水、气下的分解作用,有利于提高钢的耐大气腐蚀。

     

    Abstract: The relation between atmospheric corrosion resistance and the composition and microstructure of scales of weathering steel is discussed The scale of cold-rolled plates consists of lepidocrocites,iron hydroxides and dispersed iron particles. Comparing with that of carbon steel, the atmospheric resistance of weathering steel is very good, as lepidocrocites grow just adjacent to iron matrix. For the scales of carbon steel the iron matrix was not protected fron atmospheric corrosion for iron hydroxide was made as "harbour" between scale and metal. Magnetites and hematites were formed on the surface of hot-rolled plates.
    The scale with developed magnetite and a sawtooth structure connected with matrix coule provide a good protection to the matrix.The rare earth added made the steel cleaner and inclusions more g ranular. It seems that rare earth in the steel inhibited the decomposition of magnetite under the reaction with water and air. The steel treated by rare earth had better atmospheric corrosion resistance.

     

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