原颗粒边界问题和热处理裂纹形成原因的研究

The Formation of Cracks in a Nickel-base P/M Superalloy During Heat Treatment

  • 摘要: 业已证实,粉末高温合金中原颗粒边界(PPB)问题严重影响合金性能。本文研究了FGH95合金PPB对淬火裂纹的影响,通过对淬火开裂后样品断口形貌、析出相类型、表面俄歇谱化学成分分析找出淬火时裂纹形成的原因和控制因素。
    实验结果和分析表明;造成淬火裂纹形成的两种机制,开裂严重的是由于PPB碳化物及在其外表面形成富氧层破坏合金的连续性,促使沿原颗粒边界断裂。开裂不严重的是由于γ相界析出大块γ'相其周围贫A1,Ti区形成易氧化层,促使沿γ相界断裂。
    基于两种机制的提出,可以较好地说明影响淬火裂纹形成的主要原因是氧的污染和不适宜的淬火冷却速度。

     

    Abstract: The effect of structural defects on the formation of quench cracks in a Nickel-base P/M superalloy was studied. The serious quench crack is due to the presence of rich-oxygen layer on the.Particle surface and the formation of PPB carbides destroying the continuity of the alloy and promoting fracture along the previous particle boundaries. The slight quench crack is due to the precipitation in a coarse form at the grain boundaries. The coarseγ' precipitates are surrounded by zones depleted Al,Ti froming oxide layers which promote the fracture path along the grain boundaries. The major reason of the formation of quench cracks is the contamination of oxygen in the early processing or unsuitable quench cooling rate during heat treatment.

     

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