廉价R-Fe-B系烧结永磁材料的制备

The Study of Cheap R-Fe-B Syetem Sintered Permanent Magnetic Materials

  • 摘要: 为了综合利用我国稀土资源,降低Nd-Fe-B永磁合金的成本,研究了廉价(Nd、Pr)-Fe-B和(Ce、Nd、Pr)-Fe-B永磁材料的化学成分,制造工艺与磁性能的关系及其变化规律。添加Al可以大幅度提高合金的矫顽力。(Nd、Pr)-Fe-B合金最佳磁性能:Br=1.25T,MHc=714.3kA/m,(BH)max=297.5kJ/m3。(Nd、Pr)1-yCey-Fe-B合金的磁性能随Ce含量增加而降低。研究测定了合金的居里温度609~590K,剩磁可逆温度系数-0.094~-0.119%/K。观察分析了合金的显微组织,并测定了合金的密度,硬度及电阻率。

     

    Abstract: For comprehensive utilization of the rare earth resources in our puntry and to decrease the cost of Nd FeB magnets, the relationshi s between the magnetic properties and composition, processing of the cheap R-Fe-B system permanent magnets have been studied in this paper (R=Pr + Nd, or R=Ce + Pr + Nd). By addition of Al, the coercivity of alloy increases.The optimum magnetic properties of (NdPr)-Fe-B alloy are. Br=1.25T.MHc=714.3kA/m,(BH)m=297.2kJ/m3.The magnetic properties of (PrNd)1-y Cey-Fe-B alloy(y=0~0,5)decrease with increasing Ce content. The magnetic properties are as follows:Br=1.25T, MHc=825.4 kA/m, (BH)m=297.5kJ/m3 for the alloy of y=0.03; Br=1.20T, MHc=563.6kA/m, (BH)m=246kJ/m3 for the alloy of y=0.3, Br=1.13T, MHc=492kA/m, (BH)=222.2kJ/m3 for the alloy of y=0.4; (BH)=174.6kJ/m3 for the alloy of y=0.5. The curie temperature of the alloys is about 609~590K. The reversible temperature coefficient of residual induction is about-0.094~-0.119%/K, The microstructure, density, hardness, specific resistivity of the alloys have been observed and measured respectively.

     

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