R1+εFe4B4化合物的超空间群对称

The Superspace Group of R1+εFe4B4 Compounds

  • 摘要: 本文从Fe-B亚结构和R亚结构各自的对称性出发,由超空间群理论对R1+εeB4化合物的结构对称性进行了研究,结果表明,其对称性可由PS1S1P4/nmm得到一般性的描述。

     

    Abstract: The crystal structures of R1+εFe4B4 compounds which were found in the permanent magnets R-Fc-B systems arc all built based on the two interpenetrating substructures. Fe-B substructure and R substructure, both have tetragonalsymmetry. Since the two substructures do not have the same periodicities in c direction, R1+εFe4B4 compounds form the so called Chimney-Ladder structureor Vernier structure which may belong to the incommensurate composite crystal structure. The translation symmetry of the incommensurate structure do not exist in three dimensional space and the superspace group theory has been developed for the description of the symmetry of incommensurate structure. In this paper, the superspace group theory is applied to the R1+εFe4B4 compounds. The result shows that the symmetry of R1+εFe4B4 compounds can be descripted by the general form PS1S1P4/nmm

     

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