Cu-Zn-Al合金中热弹性马氏体转变理论
Theory for Thermoelastic Martensitic Transformation in A Cu-Zn-Al Alloy
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摘要: 把已建议的热弹性马氏体转变唯象理论,应用到Cu-Zn-Al合金中,得到常规单位下的静态自由能。将其与经典理论的相变自由能比较发现,在约20%—70%马氏体的线性变化范围,单位马氏体转变引起的界面能为常数,而引起的弹性能随马氏体量正比地增加。此外,上述唯象理论中的“摩擦准焓”和“摩擦准熵”,均分别化为常规的焓和熵的单位,更便于探讨其物理意义。Abstract: The phenomenological theory for the thermoelastic martensitic transformation suggested by the authors before is applied for Cu-29% Zn-3% Al alloy. The free energy function as well as the friction quasi-enthalpy and friction quasi-entropy, are obtained in SI units. Comparing with the clastic theory, the free energy can be broken into three parts: the chemical free energy, the interfacial energy and the elastic strain energy. In the range of 20%-70% M in the alloy, the interfacial energy per unit martensite formation is constant and the elastic strain energy per unit martensite formation is a linear function of martensite percent.