碱土金属复卤化物的能隙计算及化学键离子性的修正
Calculation of Energy Gap on Alkaline Earth Mixed Halides and Correction of the Chemical Bond Ionicity
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摘要: 从Lorents固态电子理论出发,导出一能隙的近似计算公式,表明固体的电子态和晶体结构决定了固体的能隙。对碱土金属复卤化物的能隙进行了计算,结果合理。同时考虑电负性差和原子间距,对传统化学键离子性进行了修正。计算结果和理论分析都表明,修正后的离子性能更合理地表征化合物的化学键性质。Abstract: A semi-empirical formula for energy gap calculation is obtained from the Lorentz electron theory of solids. The calculated results of energy gap on alkaline earth mixed halides are reasonable. The classical bond ionicity is corrected from the consideration of both the electronegativity difference and bond distance. It is revealed that the corrected ionicity is more suitable to characterize the chenmical bonds.