Nb(V)在FLINAK熔盐中的暂态电极过程
Transient Electrochemical Process of Nb(V) in FLINAK Melt
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摘要: 采用记时电流法和记时电位法对5价铌Nb(V)在FLINAK熔盐中的氧化-还原过程进行了研究。结果表明,Nb(V)(K2NbF7)在FLINAK熔盐中的电化学还原经历一个电化学-化学-电化学反应(ECE)途径。Nb(V)在FLINAK熔盐中的还原反应是单电子和4电子两步电化学反应过程。Abstract: The redox process of Nb(V) in (K2NbF2) in FLINAK melt has been by studied using chronopotentiometry and chronoamperometry. The results show that the electrochemical reduction of Nb(V) in FLINAK melt goes through an electrochemical-chemical-electrochemical reaction(ECE) process. The electrochemical reaction of Nb (V) in FLINAK melt is a mono-electron and four-electron transfer process.
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