固体颗粒在液相中的分散

Dispersion of Solid Particles in Liquid Media

  • 摘要: 采用沉降分析法研究了二氧化硅、重质碳酸钙、滑石和石墨4种颗粒在水、乙醇和煤油3种介质中的分散行为及表面活性剂对分散行为的影响。亲水的二氧化硅和重质碳酸钙在水中得到良好分散,在煤油中产生强烈聚团,而天然疏水的滑石和石墨颗粒则在水中聚团,在煤油中充分分散,颗粒在水与乙醇的比例为1:1的混合液中分散效果最好。表面活性剂在水和煤油中对颗粒分散的影响完全相反,颗粒在煤油中的分散行为随表面活性剂浓度变化而周期性的波动。

     

    Abstract: The dispersion behaviors of solid particles of silica, calcite, talc and graphite in water, ethanol and kerosene media and the effect of certain surfactants such as sodium oleate on the dispersion behavior have been studied. It was found that hydrophilic particles, such as silica and calcitc particles, which have naturally hydrophilic surface and manifest good dispersion behavior in water at suitable pH. tend to aggregate in kerosene; while the naturally hydrophobic talc and graphite particles, generally having a tendency to aggregate in water, disperse well in kersene. It was discovered that dispersion behavior of the particles in the mixture of water and ethanol are much better than separately in water or in pure ethanol media, the maximum dispersion occurs in the mixture of water and etlianol with ratio 1:1.The effect of surfacianus is completely opposite in water and kerosene. Furthermore, in kerosene media the dispersion behavior of particles fluctuates periodically with the increase of surfactant concentration.

     

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