低温Al2O3悬浮电解新工艺的研究

A New Process of Alumina Suspension Electrolysis

  • 摘要: 研究了利用低熔点氟氯化物体系作电解质的低温Al2O3悬浮电解制铝新工艺,从20~80A电解槽上进行的电解结果,推导了电流效率的计算表达式.结果表明,影响电流效率的主要因素是槽电流和产物铝的表面积,增大槽电流和减小产物铝的表面积都能使电流效率增大.在100A电解槽上实验,当电解温度为750℃,γ-Al2O3平均粒度为1.22μm,电解质中F-和Cl-的摩尔比为1时,电流效率达到86.3%,制取1kgAl的电耗为11.73kW·h.

     

    Abstract: A new process of low temperatUre Al2O3 suspension electrolysis for producing aluminum in low melting point fluo-chloride system was investigated. Current efficiency (η)expression deduced from experiments on 20~80A electrolysis cell showed that main effects on η are the cell current and the surface of aluminum produced.Increasing cell current and diminishing aluminum surface.can both make η increase. On an electrolysis cell of about 100A capacity with the fine γ-Al2O3 (media diam. 1.22μm) and the mixture in which F-/Cl- molar ratio was 1 at 750℃,aluminum metal was obtained with 86.3% current efficiency and 11.73 kW. h specific energy consumption.

     

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