SrTiO3中离子自扩散参数评估

Assessment of Diffusion Parameters in Strontium Titanate

  • 摘要: 评估了在未掺杂SrTiO3中氧的自扩散数据,得出:(1)在SrTiO3晶体中,氧通过氧空位扩散,扩散最快的离子为O2-,其次为Sr2-,最慢的为Ti4+.(2)在1098~1623 K范围,氧分压在0.2~7.6×104Pa内变化时,得到氧在SrTiO3晶体中的自扩散系数,而位错密度和氧分压对扩散系数影响不大.

     

    Abstract: The oxygen self-diffusion paramaters in strontium titanate were assessed. The results indicated that:(1) Oxygen diffusion occurs through a vacancy mechanism in strontium titanate crystals. The ranking of the ions based on the magnitude of diffusion coefficients is oxygen strontium and titanium ion. (2) In the temperature range from 1098 to 1623 K, under an oxygen partial pressure in the range from 0.2×104 to 7.6 ×104 Pa, the temperature dependence of the oxygen diffusion coefficient in strontium titanate is obtained. The diffusivity of the oxygen diffusion in strontium titanate is insensitive to the variation of oxygen panal pressure and the dislocation density.

     

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