304和321不锈钢连铸水口结瘤的不同机理

Different Mechanisms of Clogging in Continuous Casting of Type 304 and 321 Stainless Steels

  • 摘要: 分析了304和321不锈钢连铸水口结瘤物的物相,探讨了结瘤机理.结果表明,304水口结瘤物主要由Al2O3,MgO·Al2O3和少量细小的金属颗粒构成,结瘤层较薄,对正常浇铸的影响不显著,控制钢中Al<0.01%,可改善其结瘤.321连铸水口结瘤有TiN和CaO·TiO2两种类型:TiN型结瘤物主要由TiN和少量金属组成,控制措施是保持钢中钛氮积小于3.5,Al<0.01%;CaO·TiO2型结瘤物由CaO·TiO2-MgO·Al2O3和大量金属构成,尽可能减少钢中CaO·TiO2-MgO·Al2O3双相夹杂物的数量和避免二次氧化,可改善CaO·TiO2型结瘤,适当提高浇铸温度可缓解CaO·TiO2型结瘤.

     

    Abstract: The clogs on the submerged entry nozzle of type 304 and 321 stainless steels were investigated, and the mechanisms of clogging were discussed. The results indicated that deposits on the nozzle in type 304 stainless steel consists of Al2O3, MgO·Al2O3 and some metal. Because of the thin deposits, the casting was not affected obviously and could be improved by controlling Al < 0.01 %. There are two kinds of clogging, namely TiN-type and CaO·TiO2-type clogging, in the casting of type 321 stainless steel. TiN-type clogging consists of a lot of TiN inclusions and some metal, and could be improved by Ti%·N%×103 < 3.5 and Al < 0.01% in liquid. CaO·TiO2 type clogging consists of CaO-TiO2-MgO-Al2O3 and a lot of metal, and could be improved obviously by reducing the amount of CaO-TiO2-MgO-Al2O3 inclusions in molten steel.

     

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