Q235管线钢焊接接头微区电化学行为
Electrochemical behavior of various micro-areas on the welded joint of Q235 steel
-
摘要: 研究了燃气旧管道Q235管线钢焊接接头各个微观区域在土壤模拟溶液中的电化学行为.测量了各个微区的极化曲线,测定了相关的电化学参数.结果表明,各区域的Ecorr由低至高和icorr由大至小的顺序依次为:熔合线,不完全正火区,过热区,正火区,回火区,母材,焊缝区.同一个焊接接头的七个不同热经历区域暴露于同一电解质时,也将构成一个多电极体系.其中,熔合线和不完全正火区将成为复杂多电极体系形成的原电池中的阳极,最可能遭受到优先的腐蚀溶解;焊缝区和母材区则是原电池中的阴极,腐蚀敏感性低且在一定程度上受到阴极保护.Abstract: The electrochemical behavior of welded joints of used Q235 pipeline steel was investigated in soil simulation solution. Polarization curves of various micro-areas were measured and related electrochemical parameters were acquired. The results show that the sequence of free corrosion potential from lower to higher or the sequence of free corrosion current density from higher to lower is melt run, incomplete normalized zone, overheated zone, normalized zone, tempered zone, base metal, and weld metal. These micro-areas of a welded joint compose a multiple electrode system when exposed to the same electrolyte. Melt run and incomplete normalized zone suffer corrosion dissolution firstly as the anode of a galvanic cell composed of a complex multiple electrode system, while weld area and base metal are subjected to cathodic protection as the cathode of the galvanic cell.