TC4钛合金压坯的吸氢行为
Hydrogen absorption behavior of TC4 compacts
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摘要: 利用管式氢处理炉研究了TC4钛合金压坯的温度-平衡氢分压关系以及吸氢动力学行为,测定了吸氢速率常数和激活能,并分析了吸氢反应各个阶段的反应机理.结果表明,随着吸氢温度的升高,达到平衡所需要的时间缩短,吸氢后的平衡氢分压升高.在350℃吸氢时,反应机制分别是形核长大、幂函数定律和三维扩散.在400℃吸氢时,反应机制分别是幂函数定律和三维扩散.在450~750℃吸氢时,反应机制均是三维扩散.TC4钛合金压坯吸氢反应的激活能为14.55kJ·mol-1.Abstract: The relation of equilibrium hydrogen pressure with temperature and the hydrogen absorption kinetic behavior of TC4 compacts were investigated with a tubular hydrogen treatment furnace. The rate constant, reaction mechanisms and activation energy of hydrogen absorption at different temperatures were also determined. It is found that the time to reach equilibrium decreases with increasing temperature, but the equilibrium hydrogen pressure increases with increasing temperature. The hydrogen absorption process at 350℃ is controlled by the nucleation and growth, power law and three-dimensional diffusion, the hydrogen absorption process at 400℃ is controlled by the power law and three-dimensional diffusion, while the hydrogen absorption process from 450 to 750℃ is only controlled by the three-dimensional diffusion. The activation energy for hydrogen absorption by TC4 compacts is found to be 14.55 kJ·mol-1.