卷曲后供氧差异对热轧带钢氧化皮组织及耐蚀性的影响
Corrosion behavior and structure of oxide scales formed on hot rolled strips after coiling with different oxygen supplies
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摘要: 采用扫描电子显微镜(SEM)、X射线衍射仪、盐雾实验和电化学极化方法,研究了SS400热轧带钢沿宽度方向不同位置氧化皮的组织、结构及其耐蚀性.结果表明,SS400边部取样位置的氧化皮厚度最厚且比较均匀,结构致密,存在明显的Fe3O4/Fe共析组织.SS400边部和板宽1/4处的成分主要为Fe3O4、Fe2O3和Fe,板宽中心位置的成分主要为Fe3O4和Fe.盐雾腐蚀实验表明,SS400边部腐蚀最轻,板宽1/4处次之,板宽中心位置腐蚀最为严重.动电位极化曲线测试结果显示,SS400边部的腐蚀电位明显高于其他两个位置,腐蚀电流最小.热轧带钢在卷曲后,由于带钢沿宽度方向不同位置的供氧差异,会导致氧化皮组织、结构的显著不同,进而影响氧化皮的耐蚀性.Abstract: The structure of oxide scales and corrosion resistance of SS400 hot-rolled strips at different positions in plate width were studied by scanning electron microscopy (SEM), X-ray diffraction quantitative analysis, salt spray test and electrochemical methods. The results show that oxide scales at the plate edge are the thickest, relatively uniform and compact, and there is obvious magnetite/iron eutectoid in them. Oxide scales at the edge and one-fourth of plate width mainly consist of magnetite, hematite and magnetiteiron eutectoid, but oxide scales at the center are composed of magnetite and iron. It is shown by salt spray corrosion test that the corrosion rate is the minimum at the edge, the second at one-fourth of plate width, and the most serious at the center. By potentiodynamic polarization curve test, the corrosion potential at the edge is bigger than those at the two other parts, and the current is the minimum. After the hot rolled strips being coiled, the difference in oxygen supply in the width direction leads different structures of oxide scales, which influence the corrosion resistance of oxide scales.