超低氧车轮钢中TiN夹杂析出的热力学分析及控制

Precipitation thermodynamics analysis and control of titanium nitride inclusions in extra-low oxygen wheel steel

  • 摘要: 通过对高速车轮钢中TiN夹杂物析出进行热力学分析,得到了车轮钢的液相线和固相线温度及1873K时Ti、N的活度.对TiN生成反应和钢中Ti、N溶度积进行了计算.结果表明:TiN只能在固相中生成,但在本车轮钢Ti、N含量下,固相中也没有TiN生成的条件,只有在钢液凝固前沿,由于Ti、N在两相区的富集,TiN夹杂物的生成反应得以进行.因此,在生产中,适当提高连铸二冷的冷却速率,使钢液快速凝固,减少凝固前沿Ti、N的富集时间,可减少纯TiN的析出.对本实验车轮钢中TiN夹杂的检测结果进行计算分析可知,在正常生产时铸坯冷却速率条件下,将钢中Ti的质量分数控制在3.5×10-5以下、N的质量分数控制在3.1×10-5以下,理论上可以消除TiN夹杂物的析出,改善车轮钢的疲劳性能,提高车轮的使用寿命.

     

    Abstract: The liquidus and solidus temperatures and the Ti and N activities of high speed wheel steel at 1 873 K were obtained by thermomechanically analyzing the precipitation of TiN inclusions.The formation reaction of TiN and the solubility product of Ti and N in the steel were calculated,and the results show that TiN inclusions only form in solid phase,but under the chemical composition of this wheel steel,TiN inclusions can not be produced in solid phase.Only in a solidification front,the formation reaction of TiN can take place owing to the enrichment of Ti and N in the two-phase region.During an engineering process,properly increasing the cooling rate of the secondary cooling zone in a continuous caster to make the rapid solidification of molten steel and shorten the enrichment time of Ti and N in a solidification front can decrease the precipitation of pure TiN inclusions.The calculations and analysis on detection results of TiN inclusions in the experimental wheel steel show that the best way of removing the precipitation of pure TiN inclusions in theory and improving the fatigue properties and service life of the wheel steel is controlling the content of Ti below 3.5×10-5 and the content of N below 3.1×10-5 in the steel under the condition of normal cooling rate.

     

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