细菌脱硫抑制硫化矿自燃实验研究
Experimental study on inhibiting the spontaneous combustion of sulfide ores by bacteria desulfurization
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摘要: 通过室内细菌脱硫柱浸实验,将硫化矿石颗粒表面的硫降低到临界值以下,使脱硫后矿石自燃倾向性等级下降.结果表明,44d最大脱硫率可达61.82%,脱硫率随着时间延长而逐渐增大.对矿石自燃倾向性分析显示,硫化矿石的5d氧化增重率从2.044%降低到0.902%,自燃点从209.6℃升高到319.8℃,自燃倾向性等级由Ⅰ级降为Ⅲ级,降低了硫化矿石的自燃风险.Abstract: Bacterial desulfurization and column leaching were used to decrease the content of sulfur in sulfide ores' surface to a extreme low level even below the critical value so that the spontaneous combustion tendency of the desulfurized ores weakened.The experiment results show that the maximal desulfurization rate can reach 61.82% after 44 d treatment,and gradually increases with prolonging time.Based on the analysis of the spontaneous combustion tendency of sulfide ores,it is indicated that the oxidation weight gain rate of sulfide ores in 5 d decreases from 2.044% to 0.902% while the ores' spontaneous combustion point increases from 209.6℃ to 319.8℃.As a result,the spontaneous combustion tendency downgrades from level Ⅰ to level Ⅲ and the risk of spontaneous combustion is lowered.