CSP生产Ti微合金化高强钢中纳米碳化物

Nanocarbides in Ti-microalloyed high strength steel produced by CSP process

  • 摘要: 采用光学金相、电子显微术和化学相分析的方法并结合热力学计算,分析了紧凑式带钢生产(CSP)的Ti微合金化高强钢中的析出物及其析出规律.研究发现:高强钢中存在微米尺寸的立方TiN析出和大量纳米尺寸的析出物粒子;钢中MX相(M=Ti,Mo,Cr;X=C,N)的质量分数为0.0927%,其中10 nm以下的析出物占26.9%;均热之前和均热过程TiN已基本全部析出,连轧前TiC不具备析出的热力学条件;降低钢中N和S含量、严格控制卷取温度可增加TiC的体积分数,降低γ→α相变温度可以阻止细小碳化物长大.结果表明,析出物总的沉淀强化效果约为156 MPa,并能通过化学成分和工艺的控制进一步增强.

     

    Abstract: Optical microscopy,electron microscopy and electrolytically extracted phase analysis,in combination with thermodynamic calculations,were used to study precipitates and their precipitation behavior in Ti-microalloyed high strength steel produced by CSP process.It is found that many micron-sized cubic TiN particles and a large number of nanometer precipitates exist in the steel.The mass fraction of MX phases(M=Ti,Mo,Cr;X=C,N) in the steel is 0.0927%,in which particles smaller than 10nm account for 26.9%.Thermodynamic calculations show that titanium nitride has been almost completely precipitated from the steel during or before soaking,but titanium carbide hardly precipitates before tandem rolling.Decreasing the contents of nitrogen and sulfide and controlling the coiling temperature can increase the volume fraction of titanium carbide,and decreasing the γ→α transformation temperature can prevent fine carbides from growing.These results indicate that the precipitation hardening resulting from nanometer particles is about 156MPa and the effect can be raised through controlling the chemical composition and rolling parameters.

     

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