铪对FGH97合金平衡相影响的评估

Estimation of the effect of hafnium on equilibrium phases in FGH97 PM superalloy

  • 摘要: 利用材料相图计算和材料性能模拟软件JMatPro,计算了粉末高温合金FGH97热力学平衡相及相组成,研究了不同Hf含量对平衡相和相组成的影响,并结合物理化学相分析实验和显微组织观察进行了验证分析,进而揭示FGH97合金在750℃下各相析出和Hf在相间分配的规律,认清Hf在FGH97合金的作用.结果表明:FGH97合金在750℃下的平衡相包括γ、γ'、MC、M23C6、M3B2和μ相,Hf主要存在于γ'和MC相中,并且随着Hf含量的增大,Hf在γ'和MC相中分配不同.

     

    Abstract: The stable phases and composition of FGH97 powder metallurgy(P/M) superalloy with different contents of hafnium were calculated by JMatPro software.The effects of hafnium content on the equilibrium phases and composition were studied.Meanwhile,the stable phases were analyzed and checked by physical and chemical phase analyses and microstructure observations.Then,the behaviors of phase precipitation and the character of hafnium partition in different phases were revealed and the effects of hafnium on FGH97 P/M superalloy were summarized.It is shown that the stable phases at 750℃ include γ matrix,γ' phase,MC carbide,M23C6 carbide,M3B2 boride,and μ phase.Hafnium mainly exists in γ' phase and MC carbide,and increasing the hafnium content causes the different distribution of hafnium between γ' phase and MC carbide.

     

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