H13模铸钢锭中夹杂物的分布解剖

Inclusion distribution in H13 ingots

  • 摘要: 对5.0 t H13铸锭进行了解剖,采用扫描电镜和能谱分析对铸锭中夹杂物进行了形貌和组成分析,通过TO分析和金相显微镜统计分析对铸锭中夹杂物的分布进行了研究.结果表明铸锭中氧含量较高,平均值达到27.8×10-6,必须进一步精炼;铸锭中夹杂物主要为近球形的CaO-Al2O3-SiO2夹杂,块状TiN-VN夹杂,沿晶界分布的条状VC-CrC-MoC夹杂物和少量的CaS-MnS夹杂;尺寸较大的VC-CrC-MoC夹杂物对H13钢的韧性影响较大,必须在后续热处理及精炼中加以控制;TO和夹杂物在铸锭中分布不均匀,在铸锭头部中心附近,夹杂物及总氧呈负偏聚;而在铸锭中部及锭尾中心附近,夹杂物及总氧呈正偏聚;同时,铸锭中下部大尺寸夹杂物数量比较高.为了表征夹杂物的偏聚程度,本文提出了夹杂物偏聚指数的新概念.在5 t H13铸锭头部中心夹杂物偏聚指数达到0.75~0.85,而在中下部夹杂物偏聚指数达到1.2~1.3.

     

    Abstract: Inclusions in a 5.0-t H13 ingot were studied by dissection. Morphologies and compositions of the inclusions were studied by scanning electron microscopy and energy dispersive spectrum,and the distribution of the inclusions was studied by TOanalysis and metallographic microscopy. Results show that the average total oxygen in H13 ingot is high and reaches 27.8×10-6,so further refining is required. The inclusions in H13 are mainly near-spherical CaO-Al2O3-SiO2 inclusions,angular TiN-VN inclusions,large linear VC-CrC-MoC inclusions distributed in grain boundaries,and a few CaS-MnS inclusions. Large VC-CrC-MoC inclusions are harmful to the toughness of H13 steel,which should be controlled in following refining. The total oxygen and inclusions are uneven in ingots,the segregations of inclusions and total oxygen are negative around the core of the ingot head,while they are positive in the center and the lower part of the ingot; meanwhile,it is also found that the amount of larger inclusions in the center and the lower part of the ingot is higher. Inclusion segregation index is put forward to describe the segregation degree of inclusions,which is 0.75 to 0.85 around the core of the ingot head and 1.2 to 1.3 in the center and the lower part of the ingot.

     

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