铁水预处理脱钛热力学计算与实验分析

Thermodynamic calculation and experimental study of de-titanium in hot metal pretreatment

  • 摘要: 铁水预处理脱钛已被应用到实际生产中,铁水中的硅、锰、碳、磷在脱钛的同时都存在被氧化的可能.热力学计算和热模拟实验表明,铁水温度越低越有利于脱钛反应的进行.脱钛时,铁水中硅含量随钛含量的变化呈正比例下降,锰、磷含量变化与钛含量变化关系不大.铁水中碳的氧化主要受铁水温度影响,温度越高碳越容易氧化.要做到深脱钛,需要控制得到更低的铁水硅含量、更低的铁水温度以及抑制碳的氧化.

     

    Abstract: De-titanium of hot metal pretreatment has been applied in the metallurgy industry. Carbon,silicon,manganese,and phosphorus may be oxidized during the process of de-titanium. The thermodynamic calculation and thermal simulation experiment show that low temperature is beneficial for the de-titanium reaction. The content of silicon in hot metal declines proportionally to the content of titanium,while the contents of carbon and manganese change little. The oxidization of carbon in hot metal depends on the temperature,and the higher the temperature,the easier the oxidization of carbon. To remove more titanium,a lower content of silicon and a lower temperature of hot metal are requisite. Apart from these,it also needs to control the oxidation of carbon.

     

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