铁水脱钛理论分析与实验研究

Theory analysis and experimental study on the removal of titanium from hot metal

  • 摘要: 通过对铁水喷粉脱钛热力学和动力学的分析,建立了动力学模型,计算得到在1350℃不同停留时间条件下喷吹不同粒径的脱钛剂时,脱钛、脱硅和脱碳量的变化情况.宝钢鱼雷罐喷吹富含氧化铁的脱钛剂,根据实际停留时间的计算值,分析得到其脱钛剂的颗粒直径在0.5~0.8 mm比较合适.通过感应炉实验研究了脱钛剂的脱钛与脱硅规律,结果表明:脱钛和脱硅基本同步进行,脱钛率与脱硅率比在0.8~1左右,30 min内的脱硅率或脱钛率在40%~80%之间.由此可见,喷吹高含量氧化铁的粉剂脱钛剂进行脱钛是首选,可取得良好的脱钛效果.

     

    Abstract: Based on the analysis of thermodynamics and kinetics of the titanium removal process from hot metal by the powders injection,a kinetic model was built to calculate the removal amounts of titanium,silicon,and carbon with the change in residence time in hot metal for different sizes of injected particles. With the help of the calculated actual residence time,it can be concluded that the particle size of titanium removal agents with a high content of iron oxide in the range of 0.5 to 0.8 mm is more suitable for titanium removal. The experiment in the induction furnace was performed to study the relationship between titanium removal and silicon removal of the titanium removal agents. The results show that titanium removal and silicon removal proceed synchronously,the related ratio of titanium removal amount to silicon removal amount is in the range of 0.8 to 1,and the removal efficiencies of titanium and silicon are both in 40%-80% after 30 min treatment. It is found that in the industrial practice,the particles injection with a high content of iron oxide as the titanium removal agent should be chosen firstly and the optimal effect can be attained.

     

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