转炉铁水预处理脱磷实验研究

Study on the dephosphorization of hot metal in converter

  • 摘要: 首钢京唐公司采用转炉铁水预处理脱磷工艺作为洁净钢生产平台,通过前期58炉冶炼实验,摸索出一套适和京唐公司生产实际的操作工艺,并在造渣制度、吹炼模式、温度控制等方面取得了重大突破,实现了稳定、高效生产低磷钢、超低磷钢的目标.脱磷炉终点磷的质量分数平均为0.017%,碳的质量分数为3.69%,脱磷炉终点平均温度为1350℃,并有10炉钢的脱磷炉终点磷的质量分数小于0.015%,最低为0.008%,达到了生产超低磷钢的预脱磷要求.对实验中影响脱磷效果的因素,如铁水硅含量,脱磷炉终点温度、终点碳含量、终渣碱度和氧化性等,进行了深入研究.分析表明当铁水硅的质量分数小于0.45%时,可以达到比较好的脱磷效果;脱磷炉的脱磷效果随终点温度的升高而逐渐变差,但为保证脱碳炉有足够的热量,脱磷炉终点温度控制范围为1350~1380℃;脱磷炉合理的碳含量范围应该在3.3%~3.8%之间;碱度控制在1.8~2.2即可满足脱磷炉的脱磷效果;通过增加矿石加入量,保持较高枪位可以提高冶炼过程渣中(FeO)含量,提高脱磷炉的脱磷效率.

     

    Abstract: Dephosphorization treatment was utilized in the clean steel process in Shougang Jingtang Iron & Steel United Co. Ltd. Based on the first 58 heats tests,the practical operation process were established,especially for slag making,oxygen injecting,and temperature controlling. The stable and efficient method for low-P content and ultra-low-P content steel production was obtained. According to the experiments results,the average P content (mass fraction,so as the following) in the dephosphorization converter is 0.017%,the C content is 3.69%,and the converter terminal temperature is 1 350℃. Moreover,the P content of 10 heats is below 0.015% with the lowest content of 0.008%,which meets the requirement of ultra-low-P steel. The factors which can affect the dephosphorization process,such as silicon content,carbon content,converter terminal temperature,slag basicity,and oxidizability were investigated. The results demonstrate that when the silicon content is below 0.45%,dephosphorization is relatively more efficient. As the converter terminal temperature increases,the dephosphorization result becomes worse; however,to guarantee the temperature in the de-carbon converter,the dephosphorization converter terminal temperature is fixed at 1 350 to 1 380℃. The reasonable carbon content in the dephosphorization converter is 3.3% to 3.8%. To meet the dephosphorization requirement,the basicity (R) is controlled between 1.8 and 2.2. Enhancing the ore addition and keeping the higher lance position are suggested to increase the FeO content in slag to increase the dephosphorization efficiency.

     

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