高铝钢钙处理工艺热力学研究

Metallurgy effect of calcium treatment in high grade pipeline steel

  • 摘要: 为了解决短流程生产高铝钢时水口堵塞的问题,对某厂钙处理工艺前后的钢液成分以及钢液中的夹杂物进行了系统研究,并运用Björkvall模型对其进行了热力学分析.研究结果表明喂钙量过大,钢中S过高,则浸入式水口(SEN)堵塞物主要为CaS以及含有CaS较高的复合夹杂物.根据钢液中的Al-Ca-S三元活度平衡图可知,生产Als为0.32%~0.39%高铝钢时,为防止高铝钢浇注过程中生成CaS造成水口堵塞,钢中Ca应控制在0.004 0%~0.008 5%,S应控制在0.002 0%以下.

     

    Abstract: In order to solve the nozzle clogging in the compact strip production (CSP) process of high-content aluminum steel,the steel composition and inclusions before and after the calcium treatment were analyzed,and thermomechanical analysis based on Björkvall model was also carried out. The results show that theSandCaare both too high,as a result,CaS and high-content CaS inclusions are the main causes of the clogging. According to the Al-Ca-S equilibrium diagram,when the high-content aluminum steel, whoseAls is at 0.32% to 0.39%,is prepared,in order to prevent the formation of CaS in casting process,theSin steel should be controlled less than 0.002 0% andCain the molten steel should be controlled in the range of 0.004 0% to 0.008 5%.

     

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