电脉冲处理对热镀锌镀层生长动力学影响

Effect of electro-pulse modification on the growth kinetics of hot dip galvanizing

  • 摘要: 采用正交试验的方法,研究了电脉冲处理对热镀锌镀层生长动力学的影响.以合金层生长速率时间指数为评价指标对电脉冲处理效果进行了优化.正交试验结果表明,电脉冲处理参数中电容量是主要影响因素,处理时间影响不明显,在电容量200μF,电压700 V,频率2 Hz,处理时间30 s的条件下作用效果较好.在此参数条件下的热镀锌实验结果表明:合金层的生长受到抑制,厚度减薄,组织变得均匀致密;合金层生长速率时间指数由0.717下降到0.428,合金层的生长方式由界面反应和扩散联合控制转变为仅受扩散控制.

     

    Abstract: The influence of electro-pulse modification on the growth kinetics of hot-dip galvanizing coatings was studied through an orthogonal test method. The time exponent of growth rate was taken as an evaluation index to optimize the treatment effect of electropulse modification. Orthogonal experiment results show that pulse capacitance has the most significant influence on the growth of the alloy layer, but the influence of treating time is little. The effect of electro-pulse modification would be better in the condition of the capacitance of 200 μF, the voltage of 700 V, the pulse frequency of 2 Hz, and the treating time of 30 s. Hot-dip galvanizing experimental results at these optimum parameters show that the growth of the alloy layer is inhibited, the coating thickness is decreased, and the structure is more dense and uniform. The time exponent of growth rate decreases from 0.717 to 0.428. The growth pattern of the alloy layer transforms from integrated control by interface reaction and diffusion to independent control by diffusion.

     

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