稀土对T91耐热钢动态再结晶行为影响

Effect of rare earths on the recrystallization behavior of T91 heatresistant steel

  • 摘要: 采用Gleeble-1500热/力模拟试验机进行压缩试验,研究了不同变形条件下微量稀土对T91耐热钢动态再结晶行为的影响.分析绘制了稀土加入前后实验钢的真应力-真应变曲线、再结晶-温度-时间图、再结晶图及功率耗散图,并计算了高温下实验钢的再结晶激活能.在变形温度为850~1100℃,变形速率为0.004~10 s-1变形条件下,变形温度越高和变形速率越低,动态再结晶越容易发生.稀土加入会产生固溶强化,稀土元素与碳原子发生交互作用,且在晶界处或晶界附近偏聚,使变形抗力与峰值应变均增大,再结晶激活能由354.6 kJ·mol-1提高到397.2 kJ·mol-1.另外,稀土会显著推迟再结晶发生时间,扩大再结晶的时间间隔,推迟再结晶动力学过程.

     

    Abstract: The effect of rare earths on the dynamic recrystallization behavior of T91 heat-resistant steel under different deformation conditions was investigated on a Gleeble-1500 thermo-mechanical simulator. The true stress-strain curves, recrystallization-temperature-time (RTT) map, dynamic recrystallization map and power dissipation map were drawn for the steels with and without rare earths. The recrystallization activation energies of these two kinds of steels at elevated temperatures were also calculated in this paper. It is found that under the deformation condition of the temperature of 850 to 1100℃ and the strain rate of 0.004 to 10 s-1, dynamic recrystallization happens at higher temperatures and lower strain rates. Rare earths dissolve in the matrix, resulting in solid solution strengthening. Rare earth elements interact with carbon and segregate at grain boundaries or around the matrix, leading to the increasing of peak stress and peak strain as well as the improvement of recrystallization activation energy from 354.6 kJ·mol-1 to 397.2 kJ·mol-1. In addition, rare earths delay the starting time of recrystallization greatly, extend the time interval of recrystallization, and postpone the recrystallization kinetic process.

     

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