Fe对Ni-Mn-Ga形状记忆合金相变和力学性能的影响

Effect of Fe addition on the martensitic transformation behavior and mechanical properties of Ni-Mn-Ga shape memory alloys

  • 摘要: 研究了Fe含量对Ni56Mn25-xFexGa19(x=0~10)合金的微观组织结构、相变行为、力学性能和记忆特性的影响规律.当x ≤ 4时,Ni56Mn25-xFexGa19合金仍然保持着单一的四方结构马氏体相;当x ≥ 6时,合金呈现为马氏体相和面心立方γ相组成的双相结构.相对于马氏体相,γ相为富Ni和富Fe相,其含量随Fe含量的增加而增加.随着Fe含量增加,合金的马氏体相变温度逐渐降低,其峰值温度从x=0时的356℃降低至x=10时的170℃,这主要归因于马氏体相尺寸因素和电子浓度的综合作用.通过添加Fe替代Mn在合金中引入的γ相可提高合金的强度和塑性,但最大形状记忆回复应变从x=0时的5.0%降低到x=6时的2.0%.

     

    Abstract: The microstructure, martensitic transformation behavior, mechanical properties and shape memory characteristics of Ni56Mn25-xFexGa19 (x=0-10) shape memory alloys were investigated by optical microscopy, scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, differential scanning calorimetry, and compression testing. A single phase of martensite with tetragonal structure is observed in the alloys with x ≤ 4, but dual phases with martensite and face-centered cubic γ phase are present when x ≥ 6. Compared with martensite phase, γ phase is rich in Ni and Fe, and its volume fraction increases with increasing Fe content. The martensitic transformation peak temperature decreases from 356℃ for x=0 to 170℃ for x=10, which is attributed to the comprehensive effect of the tetragonality and electron concentration of martensite. The introduction of γ phase by substituting Fe for Mn can greatly improve the strength and plasticity of the alloys. However, the shape memory strain drops from 5.0% for x=0 to 2.0% for x=6.

     

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