Al脱氧钢中氧化物对MnS析出的影响

Effect of oxides on MnS precipitation in aluminum-deoxidized steel

  • 摘要: 使用10 kg真空感应炉Al脱氧冶炼较高S含量超低氧高强度钢,钢中TO降到0.0010%,S的质量分数为0.0190%.采用ASPEX explorer全自动扫描电镜对钢中非金属夹杂物进行检测,发现98%非金属夹杂物都是弥散分布的MnS和MnS+Al2O3复合夹杂物.MnS夹杂物棱角分明,从形貌特征来看应属于第Ⅲ类硫化物.MnS+Al2O3复合夹杂物以Al2O3为核心,外层包裹MnS,其数量约占9%~32%;作为核心的Al2O3平均直径为1.5μm.其生成过程可描述为:凝固过程中,小尺寸Al2O3被推至固液两相区,而选分结晶作用使得钢中的Mn和S在凝固前沿富集,并以Al2O3作为异质形核质点析出MnS夹杂物.对凝固过程中Al2O3的推动和捕获行为进行了相关计算.计算结果表明:直径小于4μm的Al2O3可被推动,并作为MnS的异质形核质点.

     

    Abstract: High strength steel with slightly higher S content, deoxidized by aluminum, was smelted in a vacuum induction furnace of 10 kg capacity. Total oxygen in the steel was 0.0010%, and the S content reached 0.0190%. An ASPEX explorer auto-scanning electron microscope (SEM) was used to detect nonmetallic inclusions in the steel. It is found that 98% of the inclusions are dispersed MnS and MnS+Al2O3 complex inclusions. The shape of MnS inclusions is angular, belonging to type III. Al2O3 inclusions, with an average diameter of 1.5 μm, acting as nucleation for MnS precipitation, generate wrapped inclusions of MnS+Al2O3, and they rank 9% to 32% of the total inclusions. The formation process of MnS+Al2O3 can be described as follows:small size Al2O3 inclusions are pushed to liquid phase at melt steel solidification, and then Al2O3 inclusions work as the sites of MnS inclusion precipitation due to Mn and S microsegregation. However, related calculations about the pushing and engulfment behavior of Al2O3 inclusions were carried out. The calculated results indicate that Al2O3 inclusions with the size smaller than 4 μm are pushed in liquid steel, acting as heterogeneous nucleation for the formation of MnS inclusions.

     

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