阴极弧离子镀TiAlSiN涂层摩擦与磨损行为

Friction-wear behaviors of TiAISiN coatings prepared by cathodic arc ion plating

  • 摘要: 采用阴极弧离子镀法在GH4169合金表面制备了TiAlSiN涂层,通过扫描电镜和能谱仪分析了其表面和界面的形貌和能谱,用轮廓仪测试了涂层表面粗糙度.在往复式摩擦磨损试验机上进行了涂层摩擦与磨损实验,通过能谱仪分析了涂层表面磨损后点能谱和面能谱,考察了TiAlSiN涂层的摩擦因数和磨损性能,对其磨损机理进行了讨论.实验结果显示涂层表面组织结构较为致密,表面粗糙度为194.57 nm;涂层主要成分为Ti、Al、Si和N元素,Si原子细化了TiN和AlN晶粒;涂层结合界面发生了化学反应和成分的相互扩散,其结合形式为化学结合;涂层摩擦因数平均值为0.493,磨损形式为磨粒磨损;磨损痕迹面扫描结果表明,磨损后Al和Ti形成的氮化物减少,Si和N原子无明显的减少现象,涂层耐磨性增强主要依赖于Si和N形成的化合物.

     

    Abstract: TiAlSiN coating was prepared on the GH4169 alloy surface by cathodic arc ion plating, the morphologies and energy spectra of its surface and interface were analyzed by scanning electron microscopy and energy dispersive spectroscopy, respectively, and the surface roughness was tested by profilometry. Friction and wear test of the coating was performed on a reciprocating friction testing machine, the point energy spectra and plane energy spectra after wear were analyzed by energy dispersive spectroscopy, the friction coefficient and wear property of the coating were studied, and the wear mechanism was discussed. Experimental results show that the structure of the coating surface is compact and the surface roughness is 194.57 nm. The coating is mainly composed of Ti, Al, Si and N elements, and the grains of TiN and AlN are refined by Si atoms. Chemical reactions and mutual diffusion of elements occur in the coating interface, and the combining form is chemical bonding. The average friction coefficient of the coating is 0.493, and the wear form is abrasive wear. The plane scanning results of wear traces indicate that Al and Ti nitrides in the coating decreases after wear, Si and N atoms have no significant reduction, and the increase in wear resistance of the coatings is mainly dependent on the compound formed by Si and N atoms.

     

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