Fe—Cr—O体系碳还原产物的形态

Morphology of products from the carbon reduction of Fe-Cr-O systems

  • 摘要: 研究了不同温度和不同时间条件下C还原Fe-Cr-O体系所得产物的形态,样品主要包括FeCr2O4+C和Fe2O3+2Cr2O3+C两种体系.两种样品的还原度均随温度升高而升高,反应接近平衡时还原率均在90%以上.C还原FeCr2O4和Fe2O3-Cr2O3的过程大致相同,且最终还原产物基本组成均为Fe-Cr-C合金和金属碳化物(主要为Cr7C3).针对最终还原产物中Fe-Cr-C合金和金属碳化物的含量提出了一种估算方法,其估算结果与理论计算结果基本吻合.结果显示,最终产物中Fe-Cr-C合金量随温度升高而升高,碳化物含量随温度升高而降低,且不同温度条件下所获得的Fe-Cr-C合金成分不同.

     

    Abstract: The morphology of the reduction products of Fe-Cr-O systems by C at different temperatures and time intervals was studied in this paper. The samples include two systems of FeCr2O4 +C and Fe2O3 +2Cr2O3 +C. It is found that the reduction degrees of the two samples increase with increasing temperature, and the reduction degree can be above 90% when the reaction is close to balance. The reduction processes of FeCr2O4 and Fe2O3-Cr2O3 are similar and the final reduction products are composed of Fe-Cr-C alloys and metal carbides (mainly Cr7C3). A method was proposed to estimate the contents of Fe-Cr-C alloys and metal carbides in the final reduction products, and the estimated results agree with the calculated data. It is shown that the content of Fe-Cr-C alloys increases while the content of metal carbides decreases with increasing temperature, and the composition of Fe-Cr-C alloys varies with temperature.

     

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