316L不锈钢中氮气合金化行为

Nitrogen alloying behavior of 316 L stainless steel

  • 摘要: 通过FactSage热力学计算软件和实验室实验研究了在常压和真空条件下温度、氮分压和碳含量对316L不锈钢中氮溶解度的影响.结果表明:钢中氮的溶解度随着温度的降低而升高,随着氮分压的增大而增大,随着钢液碳含量的增加而减少,其中氮分压对钢液氮溶解度的影响最大.不同吹氮条件下氮溶解度实测值与FactSage热力学软件计算值较吻合.生产控氮型316L不锈钢可以在吹氧脱碳阶段实现,生产氮质量分数大于0.10%的中氮型316L不锈钢,只能在氮分压大于30kPa的加料阶段以及破真空后大气微调阶段实现.

     

    Abstract: The influences of liquid steel temperature,nitrogen partial pressure,and carbon content on the nitrogen solubility in 316 L stainless steel under normal atmosphere and vacuum were studied by the Factsage thermodynamic calculation software and laboratory experiments. Results show that nitrogen solubility increases with decreasing the liquid steel temperature,increasing the nitrogen partial pressure,or decreasing the carbon content. The nitrogen partial pressure is the most important one among the three parameters.The thermodynamic calculation results are in coincidence with the measurement results in different nitrogen blowing processes. Producing 316 LN with the N content of 0.05%- 0.10%(mass fraction) could be conducted during oxygen blowing. Producing 316 LN with the N content of 0.10%- 0.40% should be carried out during charging(the nitrogen partial pressure must be over 30 kPa) and under atmospheric pressure.

     

/

返回文章
返回