轴承钢中夹杂物分析

Analysis on inclusions in bearing steels

  • 摘要: 对轴承钢热轧板中的夹杂物以及浇铸过程结晶器浸入式水口上的结瘤物进行了电镜检测.发现轧板试样中夹杂物类型主要是TiN、MgO·Al2O3和MnS以及少量的CaS,尺寸大多在20μm以内,除此之外,还观察到一些大尺寸MgO·Al2O3和Al2O3夹杂物及其伴生的裂纹.通过对水口结瘤物的检验分析,发现结瘤物主要以MgO·Al2O3尖晶石类夹杂物为主,还有少量的MgO-Al2O3-CaO系夹杂物,此外还含有部分凝钢.结瘤物成分与钢水中氧化物夹杂一致,因此推测水口结瘤产生原因为钢液中的固态氧化物夹杂在浇注过程中在水口上的聚集沉淀,轧板中大尺寸夹杂可能是由水口结瘤物剥落造成.

     

    Abstract: Inclusions in hot rolled sheet of bearing steel and blockage in clogged submerged entry nozzle(SEN) were analyzed using scanning electron microscopy(SEM). It is found that the inclusions in hot rolled sheet are mainly TiN,MgO·Al2O3,MnS,and a little CaS,most of them are smaller than 20 μm. Besides,some large inclusions of MgO·Al2O3 and Al2O3 and the associated cracks are observed. By the detection on clogged nozzle,it is shown that the blockage is mainly MgO·Al2O3 spinel inclusions as well as some MgO-Al2O3-CaO system inclusions and solidified steel. The composition of blockage is consistent with that of inclusions in steel,thus it is indicated that the nozzle clogging is caused by the gathering and precipitation of solid oxide inclusions in molten steel on SEN during the continuous casting process. A possible reason for the existence of large inclusions in sheet may be the drop of blockage during casting.

     

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