超低碳钢BOF渣成分对终点C含量影响
Effect of BOF slag composition on the end-pointCcontent of ultra-low carbon steel
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摘要: 采用共存理论、动力学分析和实验验证的方法,研究转炉冶炼超低碳钢吹炼末期炉渣成分对终点C含量的影响规律,建立1853-1973 K时终点C与炉渣成分和温度的回归模型.结果表明:FeO活度受温度影响较小,主要受炉渣成分的影响;脱碳动力学条件主要受炉渣成分和温度的影响.炉渣碱度增加,终点C含量升高;渣中FeO含量增加,终点C含量迅速降低,渣中FeO质量分数应控制在12.0%-18.0%之间;渣中MgO质量分数在7.0%-13.0%范围内逐渐增加,钢液中C质量分数增加值不足0.01%;随着温度的增加,钢液中C含量降低.回归模型对冶炼超低碳钢的转炉终点C含量的预判平均误差率为±15.25%,C含量误差在±0.01%以内的炉次占69.19%.Abstract: The effect of slag composition on theC content of ultra-low carbon steel at the end of smelting was investigated by the coexistence theory,dynamics analysis and experimental verification. A regression model of end-pointC content was established with temperature and slag composition in a temperature range from 1853 K to 1973 K. The results show that the Fe O activity is little affected by temperature,while it is mainly affected by slag composition. However,the decarburization kinetics is mainly affected by slag composition and temperature. The end-pointC content increases with increasing slag basicity,but it quickly decreases with increasing Fe O content in slag,so the end-point Fe O mass fraction in slag should be controlled in 12%-18%. In addition,the increment value ofC is less than 0. 01% with the Mg O mass fraction in slag from 7% to 13%. The results also show that the end-pointCmass fraction decreases with increasing temperature. Compared with industrial results,the average error rate of the regression model for the end-pointC content in the ultra-low carbon steel is ±15. 25%,and the hit rate toC content predicted by the regression model reaches 69. 19% with a control precision of ±0. 01% for heats of the experiment.