第二相粒子与织构对高强Cu-Ni-Si系合金薄板各向异性的影响

Effects of precipitates and texture on the anisotropy of high-strength Cu-Ni-Si alloy sheets

  • 摘要: 利用利用X射线衍射、电子背散射衍射和透射电子显微镜等手段研究了Cu-Ni-Si系合金在不同固溶温度下第二相与织构对其平面各向异性的影响.结果表明:随固溶温度的升高,合金强度和伸长率均出现先升高后降低的趋势,且存在明显的各向异性;800℃固溶时,Cu'和S'为主织构,部分形变晶粒诱发少量Brass、Goss和011〈511〉取向的形成,使得合金各向异性减弱;高温固溶时(≥ 850℃),晶粒发生完全再结晶,Cu'和S'织构强度显著增加,Brass等织构减弱甚至消失,各向异性增强;850℃固溶时效后形成δ-Ni2Si析出相,并与基体满足001Cu//110δ,(010)Cu//(001)δ位向关系,温度进一步增加,第二相析出体积分数降低,有利于改善材料的各向异性.

     

    Abstract: The effects of texture and precipitates on the plane anisotropy of Cu-Ni-Si alloy under different solid-solution temperature conditions were investigated by X-ray diffraction, electron backscattered diffraction, and transmission electron microscopy. The results show that strength and elongation first increase and then decrease with increasing solid-solution temperature, exhibiting apparently anisotropy. After 800℃ solid solution, the Cu' and S' are mainly texture and the alloy has weak anisotropic properties, which correlates with the coexistence of Brass, Goss, and 011〈511〉orientation owing to deformed grains. Complete recrystallization can be obtained at high temperature solution (≥ 850℃), the Cu' and S' texture intensity increases, whereas the Brass texture weakens and disappears and the anisotropy increases. δ-Ni2Si precipitation is observed after 850℃ solution and subsequent aging, and the crystal orientation between the matrix and precipitates is 001Cu//110δ and (010)Cu//(001)δ. The fraction of nanosize precipitates decreases significantly with increasing temperature and this improves the anisotropy.

     

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