添加纳米二氧化硅对氧化铁颗粒表观黏度的影响

Effect of nano-SiO2 addition on the apparent viscosity of Fe2O3 particles

  • 摘要: 借鉴流体黏性的表征方式,引入粉体颗粒表观黏度的概念表征粉体颗粒间的相互作用力,基于能量耗散原理,利用旋转黏度计测定了含SiO2纳米添加剂的Fe2O3颗粒在不同温度条件下的表观黏度.实验结果表明,Fe2O3颗粒表观黏度随温度升高而增大,纳米SiO2的加入使颗粒表观黏度明显降低,主要原因是纳米SiO2对Fe2O3颗粒形成了包覆,抑制了颗粒间的团聚和烧结.此外,本研究利用微型流化床研究了含纳米SiO2的Fe2O3颗粒在流化还原过程中发生黏结失流的过程,进一步验证了纳米SiO2对Fe2O3颗粒表观黏度的影响.结果表明,加入纳米SiO2显著提高了还原样品的金属化率,延长了还原过程中的黏结时间;扫描电镜分析表明纳米SiO2有效包覆在Fe2O3颗粒表面,降低了铁原子的扩散活性,并充分阻隔新鲜铁之间的接触,抑制新鲜铁的烧结,从而导致Fe2O3颗粒之间难以形成黏结点,由此证明纳米SiO2对流化床内Fe2O3颗粒的还原过程中的黏结失流具有明显抑制作用.

     

    Abstract: With the depletion of high-quality ore resources at home and abroad, the supply of domestic coking coal resources has become increasingly tense, and research on the non-blast furnace ironmaking technology has become even more necessary. The fluidized ironmaking technology can directly utilize powder ore, does not need to consume coke, and has good prospects for development. However, the sticking problem limits the fluidized ironmaking technology. Therefore, the sticking mechanism of particles must be explored, and inhibition measures must be put forward. Although many researchers at home and abroad have performed numerous studies on the influencing factors and inhibiting technologies of the sticking problem, the quantitative characterization and analysis of the sticking degree have rarely been studied. Similar to the fluid viscosity, the apparent viscosity of solid particles was introduced herein to characterize the interaction force between particles. The apparent viscosity of Fe2O3 particles with nano-SiO2 were measured by a rotational viscometer based on the principle of energy dissipation. The results indicate that the apparent viscosity of Fe2O3 particles increases with the increasing temperature and significantly decreases when nano-SiO2 is added. This result could be explained by the nanoSiO 2 coating on the particles inhibiting the agglomeration and sintering among particles. Sticking occurred during the fluidization process. The reduction of Fe2O3 particles was investigated by a micro-fluidized bed to verify the effect of nano-SiO2 on the apparent viscosity of Fe2O3 particles. Consequently, the results show that adding nano-SiO2 to the Fe2O3 particles can effectively improve the metallization rate and prolong the sticking time in the reduction process. Furthermore, the scanning electron microscopy analysis exhibits that the nano-SiO 2 coating on Fe2O3 particles reduces the diffusion activity of the iron atoms, blocks the contact between fresh iron, and inhibits the sintering of fresh iron, thereby making it difficult to form sticking points. In conclusion, adding nano-SiO2 to Fe2O3 particles can effectively inhibit sticking in the reduction process of the fluidized bed.

     

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