Al含量对汽车用高强钢中夹杂物的影响

Effect of Al content on inclusions in the automobile high strength steel

  • 摘要: 应用氧氮分析、扫描电镜夹杂物自动分析、热力学计算等方法, 研究了Al含量不同的三种典型汽车用高强钢中夹杂物的数量、种类、析出温度的变化规律.结果表明, 钢中Al的质量分数从0.054%增加到1.35%, 钢中的TO质量分数从0.00150%减少到0.00075%, 夹杂物数量从38.28 mm-2减少到28.12 mm-2, 钢中夹杂物的数量呈减少趋势.随着钢中Al的质量分数的增加, 钢中氧化物夹杂的演变规律为Al2O3·MnO→MgAl2O4, 铝系夹杂物的演变规律为Al2O3→Al N, 硫化物夹杂的演变规律为MnS→MgS.热力学计算表明, Al N夹杂的生成与钢中的Al含量有关, Al含量高的钢中Al N夹杂更易生成;Al N的析出温度随着Al含量的增加而上升, 析出温度分别为1375、1528和1561 K.

     

    Abstract: With the addition of Al, the type, amount and precipitation temperature of inclusions in high strength steel for automobile will change.The characteristics of inclusions including amount, species and precipitation temperature in three typical automotive high strength steels with different Al contents were investigated by oxygen and nitrogen analysis, scanning electron microscopy (SEM) , and thermodynamic calculation.The results show that the mass fraction of Al in steel increases from 0.054%to 1.35%, the mass fraction of TOin steel decreases from 0.00150%to 0.00075%, and the number of inclusions decreases from 38.28 mm-2to 28.12mm-2, the number of inclusions in steel tends to decrease.With the increase of Al mass fraction in the steel, the evolution route of main oxide inclusions is Al2O3·MnO→MgAl2O4, the main aluminum inclusion changes from Al2O3to Al N;and the evolution route of sulfide inclusions is MnS to MgS.The thermodynamic calculations indicate that the formation of Al N inclusions is related to the Al content in the steel, and the Al N inclusions in steel with high Al content are easier to be formed.The precipitation temperature of Al N increases with the increase of Al content, and the precipitation temperatures are 1375, 1528 and 1561 K, respectively.

     

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