外加拉应力对13Cr马氏体不锈钢的腐蚀行为影响

Effect of tensile stress on corrosion behavior of 13Cr martensitic stainless steel

  • 摘要: 采用电化学测试手段(开路电位、交流阻抗谱及动电位极化曲线测试), 结合接触角测试及体视显微镜微观形貌观察探究在80 g·L-1 NaCl溶液中拉应力对L80-13Cr马氏体不锈钢钝化膜溶解与再修复机制的影响.结果表明, 拉应力大小与L80-13Cr的钝化特性存在正相关关系.随着外加拉应力的增大, L80-13Cr马氏体不锈钢的开路电位负移, 电子转移电阻减小, 线性极化电阻减小, 反应速率随着拉应力的增大而增大.而L80-13Cr马氏体不锈钢在高电位下再钝化形成的钝化区会缩短, 自腐蚀电位降低, 维钝电流密度增加.接触角测试和体视显微镜微观形貌观察发现, 拉应力使得表面接触角减小, 不锈钢表面容易发生点蚀.外加拉应力使得L80-13Cr马氏体不锈钢的表面能增加, 促进钝化膜的溶解, 并且抑制钝化膜的再生, 导致材料耐蚀性降低.

     

    Abstract: Tubes in deep wells are subjected to the mixed effects of the environment and stress and thus suffer many failures. Therefore, studying the corrosion of materials under stress deformation is necessary. This paper aims to investigate the effect of applied tensile stress on the dissolution of passive film and the repair mechanism of L80-13Cr martensitic stainless steel in solution of 80 g·L-1 sodium chloride. Electrochemical tests were employed for measurements, where the main test measurements include open circuit potential (OCP), electrochemical impedance spectra (EIS), and potentiodynamic polarization tests. Contact angle measurement was combined with microscopic morphology analysis (Zoom stereo microscope) to investigate the surface activity. The test results show that there is the positive relation between applied tensile stress and the passivation characteristic of L80-13Cr martensitic stainless steel. Increase in the applied tensile stress negatively shifts the OCP value of L80-13Cr martensitic stainless steel, decreases the electron transfer resistance (Rt) and polarization resistance (Rp), and increases the rate of reaction; however, the passivation region significantly reduces, the passivation current density (Ecorr) increases, and the self-corrosion current density decreases, which forms at a high potential. The results of contact angle test and microscopic morphology analysis show that the applied tensile stress reduces the surface contact angle and promotes the pitting of L80-13Cr martensitic stainless steel. Applied tensile stress can increase the surface energy of L80-13Cr martensitic stainless steel, promote the dissolution of the passivation film, and inhibit the regeneration of the passivation film; thus, it can deteriorate the corrosion resistance of materials.

     

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