颗粒污泥与絮体污泥占比对番茄酱废水降解效能的影响

Influence of the proportion of granular sludge and flocculent sludge on the degradation efficiency of tomato paste wastewater

  • 摘要: 以番茄酱加工废水为培养基质,以SBR反应器的运行模式探讨颗粒化过程中的颗粒污泥粒径变化及对COD、N、P的去除能力;并分析颗粒污泥和絮体污泥以不同比例共存时的污泥特性、出水水质、有机污染物降解能力和混合污泥系统的污泥最佳比例。颗粒污泥的优势粒径范围在0.45~3 mm之间,对COD、\rmNH_4^+ —N和\rmPO_4^3- —P的去除率分别达到98%以上、90%以上和90%以上。颗粒污泥质量比占总污泥50%时,对COD的去除率最高,达到98%以上,对 \rmNH_4^+—N的去除率为78.72%,出水\rmPO_4^3- —P质量浓度在1.0 mg·L−1左右,去除率可以达到70.68%,其脱氮除磷效果较好。颗粒污泥质量分数<75%时,对COD的去除率达到98%以上,对出水\rmNH_4^+ —N和\rmPO_4^3- —P去除率均达到90%以上。SVI30值低于35 mL·g−1,SVI5/SVI30接近1,MLVSS/MLSS为0.90,活性高,污泥沉降性能好,微生物生长旺盛,有望通过排出老化颗粒,控制颗粒污泥质量分数≥75%,保持絮体污泥和颗粒污泥的合适比例为10%~25%,同时,实验粒径范围控制在0.45~3.00 mm,采用双向排泥方式,将粒径大于3.0 mm的颗粒和多余的絮体污泥一起排除反应池,其有机物去除性能优异,可实现颗粒污泥的长期稳定运行,解决颗粒污泥解体问题。

     

    Abstract: The removal process of waste water sludge formed in tomato sauce processing plants was analyzed and explored. The operation mode of sequencing batch reactors (SBR) was used to explore the changes in particle sizes and the removal capacity of COD, N and P in the process of granulation; the sludge characteristics, water quality, organic pollutant degradation capacity and the optimal proportion of sludge in the mixed sludge system were analyzed when the particle sludge and flocculent sludge coexisted in different proportions. The majority of particle sizes of granular sludge are in the range of 0.45‒3 mm, and the removal rates of COD, \rmNH_4^+ —N and \rmPO_4^3- —P are over 98%, 90% and 90% respectively. When the quality ratio of granular sludge accounts for 50% of the total sludge, the removal rate of COD is the highest, which is more than 98%, the removal rate of \rmNH_4^+ —N is 78.72%, and the concentration of \rmPO_4^3- —P in the effluent is about 1.0 mg·L−1, the removal rate of can reach 70.68%. The removal of nitrogen and phosphorus is also good. When the quality proportion of granular sludge is more than 75%, the removal rate of COD is higher than 98%, and the removal rate of \rmNH_4^+ —N and \rmPO_4^3- —P is higher than 90%. SVI30 value is lower than 35 mL·g−1, SVI5/SVI30 is close to 1, MLVSS/MLSS is 0.90, with high activity, good sludge settling performance, and vigorous growth of microorganisms. Therefore, SBR is expected to discharge aged particles, control the quality proportion of granular sludge ≥75%, and maintain the required proportion of flocculent sludge and granular sludge of 10%–25%. At the same time, the particle size range is controlled at 0.45–3.00 mm. Two way sludge discharge is used to remove particles larger than 3.0 mm together with excess flocculent sludge. The reactor has excellent organic matter removal performance. It can realize the long-term stable operation, effectively remove the granular sludge, and solve the problem of granular sludge disintegration.

     

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