高强度耐腐蚀ODS−FeCrAl合金微观结构、力学性能研究进展

Research progress in microstructure and service performance of high-strength and corrosion-resistant ODS−FeCrAl alloy

  • 摘要: 氧化物弥散强化(Oxide dispersion strengthened,ODS)FeCrAl合金由于加入一定量的Al元素,使合金表面可形成一层薄而致密的Al2O3保护膜,使得合金即便在1400 ℃的水蒸汽下也不会因为腐蚀导致失效。同时,大量超细氧化物粒子的弥散强化作用使其具备优异的高温强度。这种兼具高温强度和耐腐蚀的特性使得ODS−FeCrAl合金成为非常有前景的事故容错燃料(Accident tolerant fuel , ATF)包壳候选材料,也是快堆等其他工作于高温强腐蚀环境的先进反应堆包壳的重要候选材料。Al元素的引入会使ODS铁基合金中弥散粒子的种类发生变化,进而影响其显微组织和力学性能。针对ODS−FeCrAl合金中引入Al元素所导致的显微组织变化及其对蠕变性能的影响,总结了国内外相关研究进展,旨在为适用于先进反应堆的ODS−FeCrAl合金的发展提供参考。

     

    Abstract: The demand for cleaner and more efficient new generation reactors has become increasingly urgent to solve the world’s energy supply and environmental issues such as carbon emissions. The Fukushima nuclear power plant disaster in 2011 prompted researchers to pay more attention to the safety performance of cladding tube materials in nuclear power plants under non-working conditions. Earlier, zirconium alloy, which was widely used in cladding tube materials, would cause serious accidents due to the production of explosive products after failure under the condition of beyond design-basis accident (BDBA). To avoid this problem, researchers proposed the design concept of accident tolerant fuel (ATF). ATF requires the new cladding material to retain a particular strength under the condition of BDBA and does not produce explosive products, thereby avoiding catastrophic accidents. Oxide dispersion strengthened (ODS)−FeCrAl alloy has good high-temperature strength due to its dispersion strengthening. After treatment, the presence of Al forms a thin and dense Al2O3 protective film on the surface of the alloy. This layer of Al2O3 protects the alloy, ensuring that it does not fail due to corrosion even when exposed to 1400 °C steam. This combination of high-temperature strength and corrosion resistance makes ODS−FeCrAl alloy a promising candidate for advanced reactor cladding materials like ATF. Although the introduction of aluminum improves the corrosion resistance of the alloy, it also changes the type of dispersed particles in the ODS alloy. The size of dispersed particles containing Al is usually larger than before, and their number density decrease. The state of dispersed particles in the alloy is closely related to the mechanical properties of the alloy. In this paper, the current research progress is summarized using relevant domestic and foreign documents considering the influence and control method of the microstructure of ODS−FeCrAl alloy due to the introduction of the Al element with the goal of serving as a reference for the forture development of ODS−FeCrAl alloy.

     

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