钢铁产业集聚区难处理尘泥处理与全量资源化利用进展

Progress in treating difficult-to-handle dust and sludge and full-scale resource utilization in an iron and steel industry cluster

  • 摘要: 简述了钢铁冶金尘泥现有的处理工艺,具体介绍了回转窑工艺、Oxycup工艺、转底炉工艺。钢铁冶金尘泥目前的处理工艺主要停留在尘泥资源化回收利用的前3个阶段,往往只针对含量较高的部分元素进行分离回收。钢铁产业集聚区的尘泥除了含有 Fe、Zn、Pb、K、Na 等元素,还富集了大量 In、Bi、Sn、Cd等具有高附加值的稀散元素,是宝贵的有价资源。随着国家环保法规和产业政策的要求,钢铁冶金尘泥已经到了必须100%全部回收利用的新阶段。鉴于此,提出了根据各自的成分特征进行基于产品设计的各种尘泥间的协同搭配、单元技术间的科学耦合和系统集成,实现多组分梯级分离和全量利用的技术方案,希望能够为钢铁企业冶金尘泥的全量资源化利用提供参考。

     

    Abstract: Iron and steel metallurgical dust is a solid waste produced in the production process of the iron and steel industry. It has the characteristics of many types, large quantities, complex components, and many valuable elements. Japan and Germany have realized the centralized treatment and comprehensive utilization of metallurgical solid wastes, and China’s current technological level is still far behind them. This paper briefly described the existing treatment processes of iron and steel metallurgical dust and mud and specifically introduced the most widely used pyrotechnic processes in enterprises, including the rotary kiln, Oxycup, and rotary hearth furnace processes. The current treatment process of iron and steel metallurgical dust and sludge mainly stays in the first three stages of dust and sludge resource recycling and often only separates and recovers some elements with high contents. In addition to elements such as Fe, Zn, Pb, K, and Na, dust and mud in an iron and steel industry agglomeration area are also enriched with large amounts of valuable and rare elements with high added values such as In, Bi, Sn, and Cd, which are precious materials. The ineffective treatment and recycling of a huge volume of iron and steel metallurgical dust and mud will cause serious air, water, and soil pollutions; affect the ecological environment; and endanger human life. Moreover, it will cause a considerable loss of valuable resources, which is not conducive to the rapid development of China’s industries. With the requirements of the national environmental protection regulations and industrial policies, steel metallurgical dust and sludge have reached a new stage where 100% of all dust and sludge must be recycled. In response to this, a technical solution established on the product design based on the coordination of various types of dust and mud, scientific coupling, and system integration among unit technologies was proposed according to their respective composition characteristics to achieve multicomponent cascade separation and full utilization. The full resource utilization of metallurgical dust and sludge in iron and steel enterprises provides a reference.

     

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