转炉锰矿熔融还原工业试验研究

Industrial test of smelting reduction for manganese ore in converter

  • 摘要: 为打通转炉炼钢过程锰矿熔融还原技术路径,提高锰的收得率,对锰矿熔融还原过程和提高锰收得率的工艺参数进行了热力学探讨,并在某钢厂200 t转炉上开展了工业试验研究。研究结果表明:高效稳定的铁水“三脱”预处理技术是锰矿熔融还原技术成功的基本前提;通过理论计算,在炉渣中的(MnO)质量分数为5%~10%,终点C质量分数控制在0.13%~0.36%时,终点钢液Mn质量分数可控制在0.3%以上。工业试验主要通过采用双渣法冶炼操作,在确保前期铁水低磷的条件下尽可能控制少渣量、降低炉渣中氧化铁,从而实现加入锰矿后提高锰收得率;并在现有工艺控制条件下,锰矿加入10 kg·t−1以内时,工业试验可使锰矿还原过程锰收得率超过40%,平均为51.40%;为进一步提高锰收得率,建议严格将锰矿熔融还原渣料总量控制在40~60 kg·t以内,石灰加入量控制在10~15 kg·t−1以内;研究结果为锰矿熔融还原技术的开发和应用提供重要参考。

     

    Abstract: The smelting reduction of manganese ore in the converter has been reported in China since the 1990s, and some steel enterprises have successively carried out industrial tests of this technology. However, the recovery ratio of Mn in manganese ore is low and fluctuates greatly due to various reasons such as inadequate hot-metal pretreatment, the poor bottom blowing effect of the converter furnace, and unreasonable positioning of the smelting end point. The smelting reduction of manganese ore has not been successfully applied in converter steelmaking and failed to benefit steel enterprises. In this study, the thermodynamic parameters of manganese ore melting reduction were discussed to improve the recovery ratio and yield of manganese and find a way to directly use manganese ore in a converter. The industrial test was carried out in a 200 t converter at a steel mill. Results showed that the efficient and stable ‘tri-de’ (dephosphorization/desulphurization/desiliconization) hot-metal pretreatment was the basic premise for the success of manganese ore smelting reduction. The theoretical calculation revealed that when the content of MnO in slag is 5%–10% and the terminal content of C is 0.13%–0.36%, the end-point of Mn in molten steel can be controlled above 0.3%. For an improved recovery ratio of Mn in manganese, the industrial test mainly adopted the smelting operation of double-slag operation to ensure that the amount of slag and iron oxide in the slag was reduced as much as possible under low phosphorus content in molten iron in the early stage. Under the existing process control conditions, the industrial test results showed a manganese yield of more than 40% and an average value of 51.40% when the added amount of manganese ore was under 10 kg·t−1. For an excellent manganese yield, the total amount of manganese smelting reduction slag must be strictly controlled from 40 kg·t−1 to 60 kg·t−1, and the amount of lime must be 10–15 kg·t–1. This work provides an important reference for the development and direct application of manganese ore in the converter.

     

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