铌微合金化高强钢中NbC析出相的生成机理

Formation mechanism of NbC precipitates in micro-alloyed Nb high-strength steel

  • 摘要: 微合金化与热处理工艺是提升钢材性能最主要的两种方法。本文以DH980高强钢中NbC析出相为对象,研究了铌含量分别为210 × 10–6、430 × 10–6和690 × 10–6和热处理温度分别为1000、1100、1200和1300 ℃的条件下,高强钢中NbC析出相的析出行为。使用高温硅钼炉熔炼DH980连铸坯并添加不同Nb含量进行铌合金化,再将所得水冷样置于硅钼炉中完成不同温度下的热处理实验,然后使用夹杂物自动扫描电镜对实验样品进行夹杂物扫描、统计。经分析,铌微合金化后的高强钢中主要的夹杂物为Al2O3、MnS和NbC,其中,NbC析出相的尺寸范围为0.7~6.0 μm,而1.0~2.0 μm尺寸的NbC居多。使用Factsage热力学计算软件计算NbC析出温度及析出量,随着钢中铌含量从210 × 10–6增加至690 × 10–6,NbC析出相的最高析出温度逐渐升高,分别为1125、1200和1260 ℃,NbC析出率(NbC质量与所有夹杂物质量的比值)也逐渐从0.023%增加至0.047%、0.076%。MnS的析出温度为1450 ℃,不随Nb含量的变化而变化。钢中NbC析出量随着铌含量的增加而增加,也随着热处理温度的升高而增加。当热处理温度为1300 ℃时,NbC出现回溶现象,导致析出量减少。NbC尺寸主要与初始Nb含量、热处理温度、保温时间有关,NbC尺寸会随着Nb含量、热处理温度、保温时间的提高而增加。本研究中建立了高强钢中NbC析出动力学模型,预测了钢中铌含量、热处理温度、热处理时间对NbC析出相尺寸的影响。

     

    Abstract: Microalloying and heat treatment are the most important ways to improve the steel properties . In this study, the precipitation behavior of NbC precipitates with Nb content of 210 × 10–6, 430 × 10–6, and 690 × 10–6 and heat treatment temperature of 1000, 1100, 1200, and 1300 ℃ were investigated. DH980 slab was melted in a silicon–molybdenum heating furnace with different Nb additions. The water-quenched steel samples were heated at different temperature in a furnace. The morphology and chemical composition of inclusions in steel samples were determined using an inclusion analysis system. The main inclusions in the Nb micro-alloyed high-Al high-strength steel were Al2O3, MnS, and NbC. The measured diameter of NbC precipitates ranged from 0.7 to 6.0 μm, which mainly concentrated on 1.0–2.0 μm. The precipitation temperature and amount of NbC were calculated using the thermodynamic calculation software Factsage. The initial precipitation temperature of NbC precipitates gradually increased to 1125, 1200, and 1260 ℃ as the Nb content increased from 210 × 10–6 to 690 × 10–6, respectively, and the NbC precipitation rate (the ratio of NbC mass to the mass of all inclusions) increased to 0.023%, 0.047%, and 0.076%, respectively. The precipitation temperature of MnS was 1450 ℃, which changed little with the content of Nb. Al2O3 was present at the melting temperature of steel. The amount of the precipitated NbC in steel increased with an increase in Nb content and heat treatment temperature. The NbC was dissolved in steel when the heat treatment temperature was 1300 ℃, resulting in a decrease in the precipitation of NbC. The size of the NbC precipitates was mainly influenced by the Nb content, heat treatment temperature, and heating time. With the increase in the initial Nb content, the difference in Nb content between the steel matrix and reaction boundary became larger, the diffusion driving force increased, and thus the size of NbC precipitates increased. The diffusion coefficient of Nb varied with the heat treatment temperature, which was hardly influenced by the Nb content. The diffusion coefficient increased with the increase in temperature, which promoted the diffusion of Nb. Consequently, the size of NbC increased with the temperature increased. The diffusivity of Nb increased with an increase in heating time, which also increased the size of NbC. Therefore, the size of NbC precipitates increased as the Nb content, heat treatment temperature, and heating time increased. A kinetic model of NbC precipitation in high-Al high-strength steel was developed to predict the effects of Nb content, heat treatment temperature, and heating time on the size of NbC precipitates.

     

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